HOME: Online Issues

Influence of Sodium Silicate, Sodium Aluminate, and Filicium Decipiens Charcoal on The Conductivity of Artificial Zeolite

E-mail Print PDF

mac2023

Sudibyo

Research Center for Mining Technology, National Research and Innovation Agency (BRIN), South Lampung, 35361, Indonesia

Nindia Agustin

Department of Physics, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl Prof. Dr. Soemantri Brojonegoro No. 1 Bandar Lampung

Pulung Karo Karo

Department of Physics, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl Prof. Dr. Soemantri Brojonegoro No. 1 Bandar Lampung

Suprihatin

Department of Physics, Faculty of Mathematics and Natural Sciences, University of Lampung, Jl Prof. Dr. Soemantri Brojonegoro No. 1 Bandar Lampung

Fakhrony Sholahudin Rohman

School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Pulau Pinang, Malaysia

Nur Alwani Ali Bashah

Chemical Engineering Studies, College of Engineering, Universiti Teknologi MARA, Cawangan Pulai Pinang, 13500 Permatang Pauh, Pulau Pinang, Malaysia

Abstract
Fly ash-bottom ash of coal is a solid waste in many industries and electric power plants. One method to reduce that solid waste is by using it to produce artificial zeolite. The Filicium decipiens charcoal was added into artificial zeolite to increase its performance to adsorb water pollutants. The pumice stone is also used in this work as a source of silica. The manufacture of artificial zeolite was carried out by the hydrothermal method by optimizing the composition of sodium silicate from Lampung pumice silica, sodium aluminate from aluminum scrap, and charcoal of Filicium decipiens. From the characterization of the LCR meter, the optimum artificial zeolite obtains the conductivity value from 9.14×10-6 (S/cm) to 6.09×10-6 (S/cm), confirming that artificial zeolite is a semiconductor material. The highest conductivity of artificial zeolite will increase its performance as a catalyst and absorbent. The composition of the artificial zeolite after XRF characterization was aluminum, silica, phosphorus, potassium, calcium, titanium, vanadium, chromium, Mangan, and ferrite. From the XRD characterization result obtained, the dominant phase is Zeolite-A. SEM-EDX characterization results obtained a spherical and cylindrical microstructure of artificial.

pdf

Keyword: Zeolite, Lampung Pumice, Aluminium Can Waste, Conductivity, Charcoal

DOI:https://doi.org/10.24191/esteem.v19iMarch.21187

References:

[1]Mohamed, R.M., Mkhalid, I.A. and Barakat, M.A, “Rice Husk Ash as A Renewable Source for The Production of Zeolite NaY and Its Characterization,” Arabian Journal of Chemistry, vol. 8, pp. 48-53, 2015.

[2]Ayele, L., Pérez, E., Mayoral, Á., Chebude, Y. and Díaz I, “Synthesis of Zeolite a Using Raw Kaolin from Ethiopia and Its Application in Removal of Cr (III) From Tannery Wastewater”, Journal of Chemical Technology and Biotechnology, vol. 93, pp. 146-154, 2018.

[3]Czuma, N., Baran, P., Franus, W, Zabierowski, P. and Zar?bska, K, “Synthesis of Zeolites from Fly Ash with The Use of Modified Two-Step Hydrothermal Method and Preliminary SO2 Sorption Tests”, Journal Adsorption Science and Technology, vol. 37, pp. 61-76, 2018.

[4]Prajaputra, Vicky., Abidin, Zaenal. and Widiatmaka, “Methylene Blue Removal Using Developed Material from Volcanic Ash Soils”, International Journal of Scientific and Technology Research, vol. 8, pp. 706-709, 2019.

[5]Mahaddilla, Febri Melta. and Putra, Ardian, “Pemanfaatan Batu Apung sebagai Sumber Silika dalam Pembuatan Zeolit Sintetis”, Jurnal Fisika Unand, vol. 2, pp. 262-268, 2013.

[6]Pasaribu, K.A., “Efek Komposisi Zeolit-Serbuk Kayu dan Suhu Sintering terhadap Karakteristik dalam Pembuatan Keramik Berpori dengan Menggunakan PVA sebagai Perekat”, Resipository Universitas Sumatera Utara, Medan, 2011.

[7]Murniati, Hidayat, Nurul. dan Mudasir, “Pemanfaatan Limbah Abu Dasar Batubara sebagai Bahan Dasar Sintesis Zeolit dan Aplikasinya sebagai Adsorben Logam Berat Cu (II)”, Prosiding Seminar Nasional Penelitian, Pendidikan dan Penerapan MIPA, Universitas Gadjah Mada, Yogyakarta, 2009.

[8]Warsito, S., Sriatun. dan Taslimah, “Pengaruh Penambahan Surfaktan Cetyltrimethylammonium bromide (n-CTMABr) pada Sintesis Zeolit-Y”, Skripsi, Fakultas MIPA, Universitas Diponegoro, 2008.

[9] Weitkamp, J. and Puppe, L., “Catalysis and zeolites: fundamentals and applications”, Springer Science & Business Media, Germany, 1999

[10] Austin, G.T. and Jasjfi, E., “Industri Proses Kimia”, 5thEdition, Erlangga Publisher, Jakarta, 1996.

[11] Indah Saraswati, “Zeolite-A Synthesis from Glass”, Jurnal Sains dan Matematika, vol. 23 (4), pp. 112-115, 2015.

[12]Zamani, H. A., Mina, R., Mohammad, R. A. and Soraia, M, “Al3+- Selective PVC Membrane Sensor Based on Newly Synthesized 1,4-bis[o-(pyridine-2-carboxamidophenyl)]-1,4-dithiobutane as Neutral Carrier”, International Journal of Electrochemical Science, vol. 9, pp. 6495 -6504, 2014.

[13]Irmanto and Suyata, “Optimasi Penurunan Nilai BOD, COD dan TSS Limbah Cair Industri Tapioka Menggunakan Arang Aktif dari Ampas Kopi”, Molekul, vol. 5, pp. 22-32, 2010.

[14]Irzaman., Maddu, A., Syafutra, H. and Ismangil, A, “Uji Konduktivitas Listrik dan Dielektrik Film Tipis Lithium Tantalate (LiTaO_3)Yang Didadah Niobium Pentaoksida (Nb_2 O_5 )Menggunakan Metode Chemical Solution Deposition”, Prosiding Seminar Nasional Fisika, Institut Pertanian Bogor, 2010.

[15]Susmitra, R, “Analisis Sifat Listrik Polimer Polianilin (PANi) Terhadap 78 Penambahan Abu Dasar sebagai Elektroda Kapasitor”, Skripsi, Universitas Andalas, 2012.

[16]Hamidah, Alfi., Karo Karo, Pulung. and Suroto, Bambang Joko, “Kajian Konduktivitas Listrik Zeolit pada Perlakuan Termal 150°C, 250°C, 350°C dan Potensinya sebagai Elektrode Superkapasitor”, Jurnal Teori dan Aplikasi Fisika, vol. 5, pp. 65–69, 2016.

[17]S. Dur, “Zeolite Processing as Heavy Material,” J. Sains, Mat. dan Terap., vol. 1, no. 2, pp. 33–45, 2017, doi: 10.30829/zero. v1i1.1457.

[18]Hossein, Ghasemi Mobtaker., Hossein, Kazemian., Ali, Namdar Muhammad., Ali Malekinejad.  and Reza, Pakzad Mohammad, “Ion Exchange Behavior of Zeolites A and P Synthesized Using Natural Clinoptilolite, Iran”, Journal Chemical, vol. 27, pp. 111-117, 2008.