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Experimental investigation on density, kinematic viscosity and calorific value of sunflower oil - pentanol binary biofuel blend

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sep2024

Hazim Sharudin

Faculty of Mechanical Engineering, Universiti Teknologi MARA, Cawangan Johor, Pasir Gudang Campus, 81750 Masai, Johor, Malaysia

Sharzali Che Mat

Faculty of Mechanical Engineering, Universiti Teknologi MARA, Cawangan Pulau Pinang, Permatang Pauh Campus, 13500 Permatang Pauh, Pulau Pinang, Malaysia.

Nur Irsalina Huda Nazri

Faculty of Mechanical Engineering, Universiti Teknologi MARA, Cawangan Pulau Pinang, Permatang Pauh Campus, 13500 Permatang Pauh, Pulau Pinang, Malaysia.

Muhammad Arif Ab Hamid Pahmi

Faculty of Mechanical Engineering, Universiti Teknologi MARA, Cawangan Pulau Pinang, Permatang Pauh Campus, 13500 Permatang Pauh, Pulau Pinang, Malaysia.

Azmi Husin

Faculty of Mechanical Engineering, Universiti Teknologi MARA, Cawangan Pulau Pinang, Permatang Pauh Campus, 13500 Permatang Pauh, Pulau Pinang, Malaysia.

Noor Iswadi Ismail,

Faculty of Mechanical Engineering, Universiti Teknologi MARA, Cawangan Pulau Pinang, Permatang Pauh Campus, 13500 Permatang Pauh, Pulau Pinang, Malaysia.

Mahamad Hisyam Mahamad Basri

Faculty of Mechanical Engineering, Universiti Teknologi MARA, Cawangan Pulau Pinang, Permatang Pauh Campus, 13500 Permatang Pauh, Pulau Pinang, Malaysia.

Rozaini Othman

Faculty of Mechanical Engineering, Universiti Teknologi MARA, Cawangan Pulau Pinang, Permatang Pauh Campus, 13500 Permatang Pauh, Pulau Pinang, Malaysia.

Abstract

The usage of fossil fuels as the main energy source has become a serious problem due to concerns over environmental pollution and the rising fuel prices worldwide. Straight Vegetable Oil (SVO), such as Pure Sunflower Oil (PSO), is a possible alternative biofuel to petroleum diesel fuel because of its physical qualities identical to fossil fuel. However, the higher viscosity and density of SVO limit its direct use in combustion engines, which will cause problems such as incomplete combustion and carbon deposits in the chamber due to the high viscosity and density. This work presents an experimental investigation to determine and soptimise the key properties of the Sunflower oil-Pentanol blend, which has the potential to be used to replace the existing fossil fuel. This study proposes a binary biofuel blend of Pure Sunflower Oil (PSO) with higher alcohol Pentanol (PEN). Design-Expert software is used to formulate, optimise, and predict the key properties of this binary biofuel blend. Based on mixture design analysis, a total of 8 blend ratios were obtained, which are 100PSO, 50PSO50PEN, 100PSO, 75PSO25PEN, 100PEN, 50PSO50PEN, 100PEN, and 25PSO75PEN. The developed model and experimental data for the density, kinematic viscosity, and calorific value models all yielded good results, with R² values of 0.9999, 1.0000, and 0.9949, respectively. All these responses meet the ASTM D6751 requirements for biodiesel and are suitable for use in a compression-ignition engine.

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Keyword: Alternative biofuel, Binary blend,  Mixture design, Pure vegetable oil

DOI:10.24191/esteem.v21iSeptember.4680.g5013

References:

[1]          Golikova, A., Shasherina, A., Anufrikov, Y., Misikov, G., Kuzmenko, P., Smirnov, A., Toikka, M., & Toikka, A., “Excess Enthalpies Analysis of Biofuel Components: Sunflower Oil–Alcohols Systems,” International Journal of Molecular Sciences, vol. 25, no. 6, p. 3244, 2024. Available:https://doi.org/10.3390/ijms25063244

[2]          S. Che Mat, M. Y. Idroas, M. F. Hamid, and Z. A. Zainal, “Performance and emissions of straight vegetable oils and its blends as a fuel in diesel engine: A review,” Renew. Sustain. Energy Rev., vol. 82, no. February, pp. 808–823, 2018. Available:https://doi.org/10.1016/j.rser.2017.09.080

[3]          B. Sajjadi, A. A. A. Raman, and H. Arandiyan, “A comprehensive review on properties of edible and non-edible vegetable oil-based biodiesel: Composition, specifications and prediction models,” Renew. Sustain. Energy Rev., vol. 63, pp. 62–92, 2016. Available:https://doi.org/ 10.1016/j.rser.2016.05.035

[4]          S. Che Mat, M. Y. Idroas, Y. H. Teoh, and M. F. Hamid, “Optimisation of viscosity and density of refined palm Oil-Melaleuca Cajuputi oil binary blends using mixture design method,” Renew. Energy, vol. 133, pp. 393–400, 2019. Available:https://doi.org/10.1016/j.renene.2018.10.017

[5]          Polat, F., Sar?demir, S., Gad, M. S., El-Shafay, A. S., & A?bulut, Ü., “Enhancing diesel engine performance, combustion, and emissions reductions under the effect of cerium oxide nanoparticles with hydrogen addition to biodiesel fuel,” International Journal of Hydrogen Energy, vol. 83, pp. 884-896, 2024. Available:https://doi.org/10.1016/j.ijhydene.2024.08.031

[6]          V. Ariharan and N. Parameswaran, “Studies on Sun Flower Oil for Its Potential Use As Biodiesel,” Asian J. Pharm. Clin. Res., vol. 9, no. 1, 2016. [Online]. Available: http://innovareacademics.in/journals/index.php/ajpcr/article/view/10023

[7]          Dhanarasu, M., RameshKumar, K. A., & Maadeswaran, P., “Effect of acetone as an oxygenated additive with used sunflower oil biodiesel on performance, combustion and emission in diesel engine,” Environmental Technology, vol. 43, no. 24, pp. 3682-3692, 2022. Available:https://doi.org/10.1080/09593330.2021.1931471

[8]          L. Aguado-Deblas et al., “Outlook for direct use of sunflower and castor oils as biofuels in compression ignition diesel engines, being part of diesel/ethyl acetate/straight vegetable oil triple blends,” Energies, vol. 13, no. 18, 2020. Available:https://doi.org/10.3390/en13184836

[9]          L. Aguado-Deblas et al., “Biofuels from Diethyl Carbonate and Vegetable Oils for Use in Triple Blends with Diesel Fuel: Effect on Performance and Smoke Emissions of a Diesel Engine,” Energies, vol. 13, no. 24, p. 6584, 2020. Available:https://doi.org/10.3390/en13246584

[10]        Uyar, M. M., Ç?tlak, A., & Demirpolat, A. B.,  “Investigation of performance and emission values of new type of fuels obtained by adding MgO nanoparticles to biodiesel fuels produced from waste sunflower and cotton oil,” Industrial Crops and Products, vol. 222, p. 119712, 2024. Available:https://doi.org/ 10.1016/j.indcrop.2024.119712

[11]        Siyal, A. A., Mohamed, R. M. S. R., Musa, S., Rassem, H. H., & Khamidun, M. H., “A review of the performance of geopolymer catalysts for biodiesel production,” Biomass and Bioenergy, vol. 190, p. 107373, 2024. Available:https://doi.org/10.1016/j.biombioe.2024.107373

[12]        Vergel-Ortega, M., Valencia-Ochoa, G., & Duarte-Forero, J., “Experimental study of emissions in single-cylinder diesel engine operating with diesel-biodiesel blends of palm oil-sunflower oil and ethanol,” Case Studies in Thermal Engineering, vol. 26, p. 101190, 2021. Available:https://doi.org/10.1016/j.csite.2021.101190

[13]        Dhanarasu, M., RameshKumar, K. A., & Maadeswaran, P., “Effect of acetone as an oxygenated additive with used sunflower oil biodiesel on performance, combustion and emission in diesel engine,” Environmental Technology, vol. 43, no. 24, pp. 3682-3692, 2022. Available:https://doi.org/10.1080/09593330.2021.1931471

[14]        Adhikesavan, C., Ganesh, D., & Augustin, V. C., “Effect of quality of waste cooking oil on the properties of biodiesel, engine performance and emissions,” Cleaner Chemical Engineering, vol. 4, p. 100070, 2022. Available:https://doi.org/10.1016/j.clce.2022.100070

[15]        Muzammil, A., Riaz, F., Nadeem, H. U., Muzammil, S., Waris, K., Samra, H., & Siddique, M. H., “Sunflower oil” in Green Sustainable Process for Chemical and Environmental Engineering and Science, pp. 31-40, Elsevier, 2021. Available:https://doi.org/10.1016/B978-0-12-821886-0.00004-X